Colloidal particle aggregation: mechanism of assembly studied via constructal theory modeling

• Scott C. Bukosky,
• Sukrith Dev,
• Monica S. Allen and
• Jeffery W. Allen

Beilstein J. Nanotechnol. 2021, 12, 413–423, doi:10.3762/bjnano.12.33

• and could be expanded upon to fit a range of colloidal systems. Keywords: colloids; constructal law; DLVO theory; interparticle interactions; nanomaterials; self-assembly; tunable systems; Introduction Constructal theory has been used to describe a number of naturally evolving processes/phenomena

• (global) currents that flow through it” [1]. The main distinction between the classical laws of thermodynamics and constructal law is the former only describes the final equilibrium state of the system while the latter describes how and through what pathway(s) the system naturally progresses to achieve